Quantum Mechanics and Atomistic Simulation

Part 1 · Oscillators and waves

1.5 The wave equation

Source: Postorino, week 1 slides, pp. 21–23, and week 2 slides, p. 1

Objectives

  1. Picture. A disturbance passed from mass to mass along a chain of springs travels without changing shape: longitudinal or transverse.
  2. Theorem. Every solution of the wave equation is ; slides towards at speed , towards .
  3. Recipe. Prove a function of solves the wave equation with the chain rule, via .
  4. Vocabulary. Wave equation (d’Alembert’s), progressive and regressive waves, longitudinal and transverse.

A chain of oscillators

Take a chain of masses joined by springs, running from to along . Move one mass a little from equilibrium and let go. Its springs push and pull its neighbours, which push and pull theirs. The disturbance (perturbazione) travels along the chain towards both increasing and decreasing .

Call the displacement from equilibrium of the mass at position at time . The disturbance can be:

  • longitudinal: the masses move along the direction of propagation (compressions and rarefactions, like sound);
  • transverse: the masses move across the direction of propagation (like a shaken rope).

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Figure 1.5.1 A chain of masses carrying a pulse. Switch between transverse and longitudinal: in both, each mass only moves a little back and forth about its own place, while the pulse travels along the chain. Press Play.
Theorem 1.5.1The wave equationslides w1, p. 21

In both cases the disturbance obeys the wave equation, or d’Alembert’s equation. It is a linear differential equation, so the superposition principle holds.

Deriving it for the chainbeyond the lectures

Masses , springs of constant , spacing at rest; mass sits at and is displaced by . Its left spring is stretched by and its right one by , so Newton’s law reads When changes little from one mass to the next (wavelengths much longer than ), Taylor expansion gives . The odd terms cancel in the sum, so , and Stiffer springs and lighter masses carry the disturbance faster. In a solid this is the speed of sound in the spring–ball model (The harmonic approximation).

The wave equation is very general: can be a position, an electric field (§2.2 Electromagnetic waves in vacuum), the surface of the sea, the density of a gas, a density of matter…

is a speed

Example 1.5.2Dimensional analysisslides w1, p. 22

With the units of , length and time:

The general solution

Theorem 1.5.3General solution of the wave equationslides w1, p. 22

with and practically any functions, regular enough to be differentiated twice. The equation is linear, so each part, the progressive wave and the regressive wave , satisfies it on its own.

Proof

Show that is a solution. Define , so depends on and only through , with and . By the chain rule:

  • first derivative in : ;
  • second in : ;
  • first in : ;
  • second in : .

Substitute into the wave equation: For the same steps with give , and again , since the sign is squared. That every solution has this form is d’Alembert’s theorem; the slide states it.

Why every solution has this formbeyond the lectures

Change variables to and . By the chain rule, and , so The wave equation becomes . So does not depend on : it is some function of alone. Integrating in , .

Which way does move? Follow the peak of a bell-shaped pulse: at it is at , at a later time at .

Proposition 1.5.4Direction of travelslides w1, p. 23

keeps its shape and slides towards increasing at speed . Likewise slides towards decreasing .

Proof

The peak has the same height, , so the argument is the same: With and , .

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Figure 1.5.2 A pulse and a one , and their . Drag the time, or press Play. Each pulse keeps its shape; where they meet they add, then pass through each other unchanged.

Superposition, both ways?

The superposition principle holds for linear differential equations. With , the week 2 slide states it in both directions:

  • if and are solutions, then is a solution;
  • if is a solution, then and are solutions as well.

“Easy proof, do it yourselves”: the first direction is Theorem 1.3.3.

WarningSlide slip

The second direction is not true as stated. Any function can be split into two pieces that are not solutions: . What holds is the first direction. In the general solution it also happens that each piece separately is a solution, as proved above; that is the sense in which the slide uses it.

Exercises

Exercise 1.5.1beyond the lectures

A pulse is released as , with m/s. Where is its peak at s?

Solution

The peak is where the argument vanishes: , so m. The shape is unchanged.

Exercise 1.5.2beyond the lectures

Which of these solve the wave equation with speed ? (a) ; (b) ; © ; (d) .

Solution

(a) yes, a function of . (b) yes: . © no: is not a sum of a function of each; check at , : , . (d) yes, for .

Exercise 1.5.3beyond the lectures

A chain has atoms of mass kg, 0.3 nm apart, with bonds of N/m. Estimate the speed of sound along it.

Solution

m/s: the right order for sound in solids.

Exercise 1.5.4beyond the lectures

At a string is at rest with shape . Show that is the solution, and describe what happens.

Solution

It is of d’Alembert’s form, so it solves the equation. At it gives . Its time derivative at is : at rest. The initial bump splits into two half-height copies running in opposite directions.